Work at UR (undergraduate coauthors underlined)
23. Bevan S. Whitehead, William W. Brennessel, Shane S. Michtavy, Hope A. Silva, Jaehwan Kim, Phillip J. Milner, Marc D. Porosoff, and Brandon R. Barnett* “Selective Adsorption of Fluorinated Super Greenhouse Gases within a Metal–Organic Framework with Dynamic Corrugated Ultramicropores.” Chemical Science 2024, 15, 5964–5972. DOI: 10.1039/D3SC07007G
22. Christopher D. Hastings, Lucy S. X. Huffman, Chandan K. Tiwari, Jolaine Galindo Betancourth, William W. Brennessel, and Brandon R. Barnett* “Coordinatively Unsaturated Metallates of Cobalt(II), Nickel(II), and Zinc(II) Guarded by a Rigid and Narrow Void.” Inorganic Chemistry 2023, 62, 11920-11931. DOI: 10.1021/acs.inorgchem.3c01335
Work prior to UR
21. Wang, H.*”; Su, G.M.; Barnett, B.R.; Drisdell, W.S.; Long, J.R.; Prendergast, D. “Understanding 2p Core-Level Excitons of Late Transition Metals by Analysis of Mixed-Valence Copper in a Metal–Organic Framework.” Phys. Chem. Chem. Phys. 2024, Advance Article. DOI: 10.1039/D4CP00662C
20. Neville, M.L.; Chan, C.; Barnett, B.R.; Hernandez, R.E.; Moore, C.E.; Figueroa, J.S.* “Three-Coordinate Monoanions of Rhodium(1–) and Iridium (1–): Isolable Examples of Coordinatively-Unsaturated Metalate Anions.” Polyhedron 2023, 116565. DOI: 10.1016/j.poly.2023.116565.
Special Issue Honoring the Career of Prof. Arnold Rheingold
19. Barnett, B.R.; Evans, H.A.; Su, G. M.; Jiang, H.Z.H.; Chakraborty, R.; Banyeretse, D.; Hartman, T.J.; Martinez, M.B.; Trump. B.A.; Tarver, J.D.; Dods, M.N.; Funke, L.M.; Börgel, J.; Reimer, J.A.; Drisdell, W.S.; Hurst, K.E.; Gennett, T.; FitzGerald, S.A.; Brown, C.M.; Head-Gordon, M.; Long, J.R.* “Observation of an Intermediate to H2 Binding in a Metal–Organic Framework.” J. Am. Chem. Soc. 2021, 143, 14884-14994. DOI: 10.1021/jacs.1c07223
18. Anastasopoulou, A.; Furukawa, H.; Barnett, B.R.; Jiang, H.Z.H.; Long, J.R.; Breunig, H.* “Technoeconomic Analysis of Metal–Organic Frameworks for Bulk Hydrogen Transportation.” Energy Environ. Sci. 2021, 14, 1083-1094. DOI: 10.1039/d0ee02448a
17. Su, G.M.; Wang, H.; Barnett, B.R.; Long, J.R.; Prendergast, D.; Drisdell, W.S.* “Backbonding Contributions to Small Molecule Chemisorption in a Metal–Organic Framework with Open Copper(I) Centers.” Chem. Sci. 2021, 12, 2156-2164. DOI: 10.1039/D0SC06038K
16. Barnett, B.R.; Parker, S.T.; Paley, M.V.; Biggins, N.; Gonzalez, M.I.; Oktawiec, J.; Long, J.R.* “Thermodynamic Separation of 1-Butene from 2-Butene in Metal–Organic Frameworks with Open Metal Sites.” J. Am. Chem. Soc. 2019, 141, 18325-18333. DOI: 10.1021/jacs.9b09942
15. FitzGerald, S.A.*; Mukasa, D.; Rigdon, K.H.; Zhang, N.; Barnett, B.R. “Hydrogen Isotope Separation within Cu-MFU-4l.” J. Phys. Chem. C 2019, 123, 30427-30433. DOI: 10.1021/acs.jpcc.9b09332
14. Barnett, B.R.; Gonzalez, M.I.; Long, J.R.* “Recent Progress Towards Light Hydrocarbon Separations Using Metal–Organic Frameworks.” Trends Chem. 2019, 1, 159-171. DOI: 10.1016/j.trechm.2019.02.012
13. Barnett, B.R.; Mokhtarzadeh, C.C.; Figueroa, J.S. Lummins, P.; Wang, S.; Queen, J.D.; Gavenonis, J.; Schüwer, N.; Tilley, T.D.; Boynton, J.N.; Power, P.P.; Ditri, T.B.; Weidemann, N.; Agnew, D.W.; Smith, P.W.; Carpenter, A.E.; Pratt, J.K.; Mendelson, N.D. “Terphenyl Ligands and Complexes.” Inorg. Synth. 2018, 37, 85-122. DOI: 10.1002/9781119477822
12. Barnett, B.R.; Neville, M.L.; Moore, C.E.; Rheingold, A.L.; Figueroa, J.S.* “Oxidative-Insertion Reactivity Across a Geometrically Constrained Metal-Borane Interaction.” Angew. Chem. Int. Ed. 2017, 56, 7195-7199. DOI: 10.1002/anie.201702151
11. Barnett, B.R.†; Labios, L.A.†; Stauber, J.M.†; Moore, C.E.; Rheingold, A.L.; Figueroa, J.S.* “Synthetic and Mechanistic Interrogation of Pd/Isocyanide-Catalyzed Cross-Coupling: π-Acidic Ligands Enable Self-Aggregating Monoligated Pd(0) Intermediates.” Organometallics, 2017, 36, 944-954. (†equal contributions) DOI: 10.1021/acs.organomet.7b00035
10. Barnett, B.R.; Figueroa, J.S. “Zero-Valent Isocyanides of Nickel, Palladium and Platinum as Transition Metal σ-type Lewis Bases.” Chem. Commun. 2016, 52, 13829-13839. Invited Feature Article. DOI: 10.1039/C6CC07863J
9. Barnett, B.R.; Rheingold, A.L.; Figueroa, J.S.* “Monomeric Chini-Type Triplatinum Clusters Featuring Dianionic and Radical-Anionic π*-Systems.” Angew. Chem. Int. Ed. 2016, 55, 9253-9258. DOI: 10.1002/anie.201604903
8. Smith, S.J.; Radford, R.J.; Subramanian, R.H.; Barnett, B.R.; Figueroa, J.S.; Tezcan, F.A.* “Tunable Helicity, Stability and DNA-Binding Properties of Short Peptides with Hybrid Metal Coordination Motifs.” Chem. Sci. 2016, 7, 5453-5461. DOI: 10.1039/C6SC00826G
7. Barnett, B.R.; Moore, C.E.; Chandrasekaran, P.; Sproules, S.; Rheingold, A.L.; DeBeer, S.; Figueroa, J.S.* “Metal-only Lewis Pairs Between Group 10 Metals and Tl(I) or Ag(I): Insights into the Electronic Consequences of Z-type Ligand Binding.” Chem. Sci. 2015, 6, 7169-7178. DOI: 10.1039/C5SC03104D
6. Barnett, B.R.; Labios, L.A.; Moore, C.E.; England, J.; Rheingold, A.L.; Wieghardt, K.; Figueroa, J.S.* “Solution Dynamics of Redox-Noninnocent Nitrosoarene Ligands: Mapping the Electronic Criteria for the Formation of Persistent Metal-Coordinated Nitroxide Radicals.” Inorg. Chem. 2015, 54, 7110-7121. DOI: 10.1021/acs.inorgchem.5b01252
5. Barnett, B.R.; Moore, C.E.; Rheingold, A.L.; Figueroa, J.S.* “Frustrated Lewis Pair Behavior of Monomeric (boryl)iminomethanes Accessed from Isocyanide 1,1-hydroboration.” Chem. Commun. 2015, 51, 541-544. DOI: 10.1039/C4CC08037H
4. Carpenter, A.E.; McNeece, A.J.; Barnett, B.R.; Estrada, A.L.; Mokhtarzadeh, C.C.; Moore, C.E.; Rheingold, A.L.; Perrin, C.L.; Figueroa, J.S.* “Direct Observation of β-Chloride Elimination from an Isolable β-Chloroalkyl Complex of Square Planar Nickel.” J. Am. Chem. Soc. 2014, 136, 15481-15484. DOI: 10.1021/ja508956q
3. Barnett, B.R.; Moore, C.E.; Rheingold, A.L.; Figueroa, J.S.* “Cooperative Transition Metal/Lewis Acid Bond-Activation Reactions by a Bidentate (Boryl)iminomethane Complex: A Significant Metal-Borane Interaction Promoted by a Small Bite-Angle LZ Chelate.” J. Am. Chem. Soc. 2014, 136, 10262-10265. DOI: 10.1021/ja505843g
2. Roberts, C.C.; Barnett, B.R.; Green, D.B.; Fritsch, J.M.* “Synthesis and Structures of Tridentate Ketoiminate Zinc Complexes that Act as L-lactide Ring-Opening Polymerization Catalysts.” Organometallics 2012, 31, 4133-4141. DOI: 10.1021/om200865w
1. Barnett, B.R.; Evans, A.L.; Roberts, C.C.; Fritsch, J.M.* “Batch Reactor Kinetic Studies on the Reductive Dechlorination of Chlorinated Ethylenes by tetrakis-(4-sulfonatophenyl)porphryn cobalt.” Chemosphere, 2011, 82, 592-596. DOI: 10.1016/j.chemosphere.2010.11.015