Publications

Work prior to UR

18. Barnett, B.R.; Parker, S.T.; Paley, M.V.; Biggins, N.; Gonzalez, M.I.; Oktawiec, J.; Long, J.R. “Thermodynamic Separation of 1-Butene from 2-Butene in Metal–Organic Frameworks with Open Metal Sites.” J. Am. Chem. Soc. 2019, 141, 18325-18333. DOI: 10.1021/jacs.9b09942

17. FitzGerald, S.A.; Mukasa, D.; Rigdon, K.H.; Zhang, N.; Barnett, B.R. “Hydrogen Isotope Separation within Cu-MFU-4l.” J. Phys. Chem. C 2019, 123, 30427-30433. DOI: 10.1021/acs.jpcc.9b09332

16. Barnett, B.R.; Gonzalez, M.I.; Long, J.R. “Recent Progress Towards Light Hydrocarbon Separations Using Metal–Organic Frameworks.” Trends Chem. 2019, 1, 159-171. DOI: 10.1016/j.trechm.2019.02.012

15. Ditri, T.B.; Barnett, B.R.; Carpenter, A.E.; Mokhtarzadeh, C.C.; Agnew, D.W.; Figueroa, J.S. “Bis-2,6-(2,4,6-trimethylphenyl)phenylformamide and Isocyanide.” Inorg. Synth. 2018, 37, 109-115. DOI: 10.1002/9781119477822

14. Ditri, T.B.; Weidemann, N.; Barnett, B.R.; Agnew, D.W.; Figueroa, J.S. “Bis-2,6-(2,6-diisopropylphenyl)aniline.” Inorg. Synth. 2018, 37, 105-108.
DOI: 10.1002/9781119477822

13. Barnett, B.R.; Mokhtarzadeh, C.C.; Figueroa, J.S. “m-Terphenyl Iodo and Lithium Reagents Featuring 2,6-Bis-(2,6-diisopropylphenyl) Substitution Patterns and a m-Terphenyl Lithium Etherate Featuring the 2,6-Bis-(2,4,6-triisopropylphenyl) Substitution Pattern.” Inorg. Synth. 2018, 37, 89-98.
DOI: 10.1002/9781119477822

12. Barnett, B.R.; Neville, M.L.; Moore, C.E.; Rheingold, A.L.; Figueroa, J.S. “Oxidative-Insertion Reactivity Across a Geometrically Constrained Metal-Borane Interaction.” Angew. Chem. Int. Ed. 2017, 56, 7195-7199. DOI: 10.1002/anie.201702151

11. Barnett, B.R.†; Labios, L.A.†; Stauber, J.M.†; Moore, C.E.; Rheingold, A.L.; Figueroa, J.S. “Synthetic and Mechanistic Interrogation of Pd/Isocyanide-Catalyzed Cross-Coupling: π-Acidic Ligands Enable Self-Aggregating Monoligated Pd(0) Intermediates.” Organometallics, 2017, 36, 944-954. (†equal contributions) DOI: 10.1021/acs.organomet.7b00035

10. Barnett, B.R.; Figueroa, J.S. “Zero-Valent Isocyanides of Nickel, Palladium and Platinum as Transition Metal σ-type Lewis Bases.” Chem. Commun. 2016, 52, 13829-13839. Invited Feature Article. DOI: 10.1039/C6CC07863J

    • Front Cover Artwork (Art credit: Jessica Peters, Ph.D.; Copyright 2016, Royal  Society of Chemistry) DOI: 10.1039/C6CC90537D

9. Barnett, B.R.; Rheingold, A.L.; Figueroa, J.S. “Monomeric Chini-Type Triplatinum Clusters Featuring Dianionic and Radical-Anionic π*-Systems.” Angew. Chem. Int. Ed. 2016, 55, 9253-9258. DOI: 10.1002/anie.201604903

8. Smith, S.J.; Radford, R.J.; Subramanian, R.H.; Barnett, B.R.; Figueroa, J.S.; Tezcan, F.A. “Tunable Helicity, Stability and DNA-Binding Properties of Short Peptides with Hybrid Metal Coordination Motifs.” Chem. Sci. 2016, 7, 5453-5461. DOI: 10.1039/C6SC00826G

7. Barnett, B.R.; Moore, C.E.; Chandrasekaran, P.; Sproules, S.; Rheingold, A.L.; DeBeer, S.; Figueroa, J.S. “Metal-only Lewis Pairs Between Group 10 Metals and Tl(I) or Ag(I): Insights into the Electronic Consequences of Z-type Ligand Binding.” Chem. Sci. 2015, 6, 7169-7178. DOI: 10.1039/C5SC03104D

6. Barnett, B.R.; Labios, L.A.; Moore, C.E.; England, J.; Rheingold, A.L.; Wieghardt, K.; Figueroa, J.S. “Solution Dynamics of Redox-Noninnocent Nitrosoarene Ligands: Mapping the Electronic Criteria for the Formation of Persistent Metal-Coordinated Nitroxide Radicals.” Inorg. Chem. 2015, 54, 7110-7121. DOI: 10.1021/acs.inorgchem.5b01252

5. Barnett, B.R.; Moore, C.E.; Rheingold, A.L.; Figueroa, J.S. “Frustrated Lewis Pair Behavior of Monomeric (boryl)iminomethanes Accessed from Isocyanide 1,1-hydroboration.” Chem. Commun. 2015, 51, 541-544. DOI: 10.1039/C4CC08037H

4. Carpenter, A.E.; McNeece, A.J.; Barnett, B.R.; Estrada, A.L.; Mokhtarzadeh, C.C.; Moore, C.E.; Rheingold, A.L.; Perrin, C.L.; Figueroa, J.S. “Direct Observation of β-Chloride Elimination from an Isolable β-Chloroalkyl Complex of Square Planar Nickel.” J. Am. Chem. Soc. 2014, 136, 15481-15484. DOI: 10.1021/ja508956q

3. Barnett, B.R.; Moore, C.E.; Rheingold, A.L.; Figueroa, J.S. “Cooperative Transition Metal/Lewis Acid Bond-Activation Reactions by a Bidentate (Boryl)iminomethane Complex: A Significant Metal-Borane Interaction Promoted by a Small Bite-Angle LZ Chelate.” J. Am. Chem. Soc. 2014, 136, 10262-10265. DOI: 10.1021/ja505843g

2. Roberts, C.C.; Barnett, B.R.; Green, D.B.; Fritsch, J.M. “Synthesis and Structures of Tridentate Ketoiminate Zinc Complexes that Act as L-lactide Ring-Opening Polymerization Catalysts.” Organometallics 2012, 31, 4133-4141. DOI: 10.1021/om200865w

1. Barnett, B.R.; Evans, A.L.; Roberts, C.C.; Fritsch, J.M. “Batch Reactor Kinetic Studies on the Reductive Dechlorination of Chlorinated Ethylenes by tetrakis-(4-sulfonatophenyl)porphryn cobalt.” Chemosphere, 2011, 82, 592-596. DOI: 10.1016/j.chemosphere.2010.11.015