Work at UR (undergraduate coauthors underlined)
24. Hope A. Silva, Bevan S. Whitehead, Chandan Kumar Tiwari, William W. Brennessel, and Brandon R. Barnett* “Installation of Copper(I) and Silver(I) Sites in a TREN-based Porous Organic Cage via Post-Synthetic Metallation.” Submitted.
23. Bevan S. Whitehead, William W. Brennessel, Shane S. Michtavy, Hope A. Silva, Jaehwan Kim, Phillip J. Milner, Marc D. Porosoff, and Brandon R. Barnett* “Selective Adsorption of Fluorinated Super Greenhouse Gases within a Metal–Organic Framework with Dynamic Corrugated Ultramicropores.” Chemical Science 2024, 15, 5964–5972. DOI: 10.1039/D3SC07007G
22. Christopher D. Hastings, Lucy S. X. Huffman, Chandan Kumar Tiwari, Jolaine Galindo Betancourth, William W. Brennessel, and Brandon R. Barnett* “Coordinatively Unsaturated Metallates of Cobalt(II), Nickel(II), and Zinc(II) Guarded by a Rigid and Narrow Void.” Inorganic Chemistry 2023, 62, 11920-11931. DOI: 10.1021/acs.inorgchem.3c01335
Work prior to UR
21. Wang, H.*”; Su, G.M.; Barnett, B.R.; Drisdell, W.S.; Long, J.R.; Prendergast, D. “Understanding 2p Core-Level Excitons of Late Transition Metals by Analysis of Mixed-Valence Copper in a Metal–Organic Framework.” Phys. Chem. Chem. Phys. 2024, Advance Article. DOI: 10.1039/D4CP00662C
20. Neville, M.L.; Chan, C.; Barnett, B.R.; Hernandez, R.E.; Moore, C.E.; Figueroa, J.S.* “Three-Coordinate Monoanions of Rhodium(1–) and Iridium (1–): Isolable Examples of Coordinatively-Unsaturated Metalate Anions.” Polyhedron 2023, 116565. DOI: 10.1016/j.poly.2023.116565.
Special Issue Honoring the Career of Prof. Arnold Rheingold
19. Barnett, B.R.; Evans, H.A.; Su, G. M.; Jiang, H.Z.H.; Chakraborty, R.; Banyeretse, D.; Hartman, T.J.; Martinez, M.B.; Trump. B.A.; Tarver, J.D.; Dods, M.N.; Funke, L.M.; Börgel, J.; Reimer, J.A.; Drisdell, W.S.; Hurst, K.E.; Gennett, T.; FitzGerald, S.A.; Brown, C.M.; Head-Gordon, M.; Long, J.R.* “Observation of an Intermediate to H2 Binding in a Metal–Organic Framework.” J. Am. Chem. Soc. 2021, 143, 14884-14994. DOI: 10.1021/jacs.1c07223
18. Anastasopoulou, A.; Furukawa, H.; Barnett, B.R.; Jiang, H.Z.H.; Long, J.R.; Breunig, H.* “Technoeconomic Analysis of Metal–Organic Frameworks for Bulk Hydrogen Transportation.” Energy Environ. Sci. 2021, 14, 1083-1094. DOI: 10.1039/d0ee02448a
17. Su, G.M.; Wang, H.; Barnett, B.R.; Long, J.R.; Prendergast, D.; Drisdell, W.S.* “Backbonding Contributions to Small Molecule Chemisorption in a Metal–Organic Framework with Open Copper(I) Centers.” Chem. Sci. 2021, 12, 2156-2164. DOI: 10.1039/D0SC06038K
16. Barnett, B.R.; Parker, S.T.; Paley, M.V.; Biggins, N.; Gonzalez, M.I.; Oktawiec, J.; Long, J.R.* “Thermodynamic Separation of 1-Butene from 2-Butene in Metal–Organic Frameworks with Open Metal Sites.” J. Am. Chem. Soc. 2019, 141, 18325-18333. DOI: 10.1021/jacs.9b09942
15. FitzGerald, S.A.*; Mukasa, D.; Rigdon, K.H.; Zhang, N.; Barnett, B.R. “Hydrogen Isotope Separation within Cu-MFU-4l.” J. Phys. Chem. C 2019, 123, 30427-30433. DOI: 10.1021/acs.jpcc.9b09332
14. Barnett, B.R.; Gonzalez, M.I.; Long, J.R.* “Recent Progress Towards Light Hydrocarbon Separations Using Metal–Organic Frameworks.” Trends Chem. 2019, 1, 159-171. DOI: 10.1016/j.trechm.2019.02.012
13. Barnett, B.R.; Mokhtarzadeh, C.C.; Figueroa, J.S. Lummins, P.; Wang, S.; Queen, J.D.; Gavenonis, J.; Schüwer, N.; Tilley, T.D.; Boynton, J.N.; Power, P.P.; Ditri, T.B.; Weidemann, N.; Agnew, D.W.; Smith, P.W.; Carpenter, A.E.; Pratt, J.K.; Mendelson, N.D. “Terphenyl Ligands and Complexes.” Inorg. Synth. 2018, 37, 85-122. DOI: 10.1002/9781119477822
12. Barnett, B.R.; Neville, M.L.; Moore, C.E.; Rheingold, A.L.; Figueroa, J.S.* “Oxidative-Insertion Reactivity Across a Geometrically Constrained Metal-Borane Interaction.” Angew. Chem. Int. Ed. 2017, 56, 7195-7199. DOI: 10.1002/anie.201702151
11. Barnett, B.R.†; Labios, L.A.†; Stauber, J.M.†; Moore, C.E.; Rheingold, A.L.; Figueroa, J.S.* “Synthetic and Mechanistic Interrogation of Pd/Isocyanide-Catalyzed Cross-Coupling: π-Acidic Ligands Enable Self-Aggregating Monoligated Pd(0) Intermediates.” Organometallics, 2017, 36, 944-954. (†equal contributions) DOI: 10.1021/acs.organomet.7b00035
10. Barnett, B.R.; Figueroa, J.S. “Zero-Valent Isocyanides of Nickel, Palladium and Platinum as Transition Metal σ-type Lewis Bases.” Chem. Commun. 2016, 52, 13829-13839. Invited Feature Article. DOI: 10.1039/C6CC07863J
9. Barnett, B.R.; Rheingold, A.L.; Figueroa, J.S.* “Monomeric Chini-Type Triplatinum Clusters Featuring Dianionic and Radical-Anionic π*-Systems.” Angew. Chem. Int. Ed. 2016, 55, 9253-9258. DOI: 10.1002/anie.201604903
8. Smith, S.J.; Radford, R.J.; Subramanian, R.H.; Barnett, B.R.; Figueroa, J.S.; Tezcan, F.A.* “Tunable Helicity, Stability and DNA-Binding Properties of Short Peptides with Hybrid Metal Coordination Motifs.” Chem. Sci. 2016, 7, 5453-5461. DOI: 10.1039/C6SC00826G
7. Barnett, B.R.; Moore, C.E.; Chandrasekaran, P.; Sproules, S.; Rheingold, A.L.; DeBeer, S.; Figueroa, J.S.* “Metal-only Lewis Pairs Between Group 10 Metals and Tl(I) or Ag(I): Insights into the Electronic Consequences of Z-type Ligand Binding.” Chem. Sci. 2015, 6, 7169-7178. DOI: 10.1039/C5SC03104D
6. Barnett, B.R.; Labios, L.A.; Moore, C.E.; England, J.; Rheingold, A.L.; Wieghardt, K.; Figueroa, J.S.* “Solution Dynamics of Redox-Noninnocent Nitrosoarene Ligands: Mapping the Electronic Criteria for the Formation of Persistent Metal-Coordinated Nitroxide Radicals.” Inorg. Chem. 2015, 54, 7110-7121. DOI: 10.1021/acs.inorgchem.5b01252
5. Barnett, B.R.; Moore, C.E.; Rheingold, A.L.; Figueroa, J.S.* “Frustrated Lewis Pair Behavior of Monomeric (boryl)iminomethanes Accessed from Isocyanide 1,1-hydroboration.” Chem. Commun. 2015, 51, 541-544. DOI: 10.1039/C4CC08037H
4. Carpenter, A.E.; McNeece, A.J.; Barnett, B.R.; Estrada, A.L.; Mokhtarzadeh, C.C.; Moore, C.E.; Rheingold, A.L.; Perrin, C.L.; Figueroa, J.S.* “Direct Observation of β-Chloride Elimination from an Isolable β-Chloroalkyl Complex of Square Planar Nickel.” J. Am. Chem. Soc. 2014, 136, 15481-15484. DOI: 10.1021/ja508956q
3. Barnett, B.R.; Moore, C.E.; Rheingold, A.L.; Figueroa, J.S.* “Cooperative Transition Metal/Lewis Acid Bond-Activation Reactions by a Bidentate (Boryl)iminomethane Complex: A Significant Metal-Borane Interaction Promoted by a Small Bite-Angle LZ Chelate.” J. Am. Chem. Soc. 2014, 136, 10262-10265. DOI: 10.1021/ja505843g
2. Roberts, C.C.; Barnett, B.R.; Green, D.B.; Fritsch, J.M.* “Synthesis and Structures of Tridentate Ketoiminate Zinc Complexes that Act as L-lactide Ring-Opening Polymerization Catalysts.” Organometallics 2012, 31, 4133-4141. DOI: 10.1021/om200865w
1. Barnett, B.R.; Evans, A.L.; Roberts, C.C.; Fritsch, J.M.* “Batch Reactor Kinetic Studies on the Reductive Dechlorination of Chlorinated Ethylenes by tetrakis-(4-sulfonatophenyl)porphryn cobalt.” Chemosphere, 2011, 82, 592-596. DOI: 10.1016/j.chemosphere.2010.11.015